doi:10.16178/j.issn.0528-9017.20220947

Abstract

CLC Number:

S156.2

Figures/Tables 3

References 55

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改性生物炭类型	农药	表现	文献
蒸汽活化稻壳生物炭	克百威	水蒸气活化进一步提高了生物炭产率和吸附量。700 ℃生产的蒸汽活化生物炭在pH值为5附近出现吸附最大值161 mg·g^-1	[27]
同时共热解热空气活化	2,4-D(2,4-二氯苯氧酸)	与传统缺氧热解产生的生物炭相比,850 ℃共热解的生物具有相似的微孔表面积(约330 m²·g^-1),但约为中孔表面积是其2.5倍,对2,4-D的吸附量达10倍以上	[37]
H₃PO₄,NaOH改性椰壳生物炭	二嗪磷	比表面积关系为BC3(NaOH改性生物炭)>BC2 (H₃PO₄改性生物炭)>BC4(原生物炭),且BC3对二嗪磷具有最大的吸附量。在pH值为7,BC3作为吸附剂剂量为5.0 g·L^-1时,二嗪磷去除率高达98.96%	[38]
ZnCl₂活化烟草生物炭	毒死蜱	与原生物炭相比,AB-ZnCl₂的SSA提高了1 775倍,二者最大吸附量分别为683.30和1 602.40 μg·g^-1	[39]
KOH活化花生壳生物炭	2,4-D	比表面积由于活化增加,最大吸附量活化生物炭250 mg·g^-1>热解生物炭3.02 mg·g^-1	[40]
掺p玉米秸秆生物炭	三嗪类	掺杂增加了表面积和生物炭上的—COOH和—PO₃基团的数量,从而促进吸附过程,来自玉米秸秆(CSWP)的掺杂生物炭,最大吸附量可达79.6 mg·g^-1	[21]
纳米石榴皮生物炭	毒死蜱	最大吸附量比石榴皮提高了25倍,10 min内吸附率约为90%	[41]
酸、碱、磁化改性700 ℃热解玉米秸秆生物炭	多菌灵	3种改性生物炭对多菌灵的吸附能力为磁化生物炭>酸化生物炭>碱化生物炭。磁化生物炭的最大吸附量达到108.1 mg·g^-1	[42]
黏土-白杨生物炭复合材料	草甘膦	复合材料比黏土和生物炭具有更好的吸附能力,吸附动力学符合准二级动力学模型,与 Langmuir模型拟合较好	[43]
载铁风车草生物炭	毒死蜱	铁浸渍的生物炭的表面比原始生物炭更复杂,更多孔,表现出比原始生物炭更高的吸附能力	[44]

改性生物炭类型	农药	表现	文献
蒸汽活化稻壳生物炭	克百威	水蒸气活化进一步提高了生物炭产率和吸附量。700 ℃生产的蒸汽活化生物炭在pH值为5附近出现吸附最大值161 mg·g^-1	[27]
同时共热解热空气活化	2,4-D(2,4-二氯苯氧酸)	与传统缺氧热解产生的生物炭相比,850 ℃共热解的生物具有相似的微孔表面积(约330 m²·g^-1),但约为中孔表面积是其2.5倍,对2,4-D的吸附量达10倍以上	[37]
H₃PO₄,NaOH改性椰壳生物炭	二嗪磷	比表面积关系为BC3(NaOH改性生物炭)>BC2 (H₃PO₄改性生物炭)>BC4(原生物炭),且BC3对二嗪磷具有最大的吸附量。在pH值为7,BC3作为吸附剂剂量为5.0 g·L^-1时,二嗪磷去除率高达98.96%	[38]
ZnCl₂活化烟草生物炭	毒死蜱	与原生物炭相比,AB-ZnCl₂的SSA提高了1 775倍,二者最大吸附量分别为683.30和1 602.40 μg·g^-1	[39]
KOH活化花生壳生物炭	2,4-D	比表面积由于活化增加,最大吸附量活化生物炭250 mg·g^-1>热解生物炭3.02 mg·g^-1	[40]
掺p玉米秸秆生物炭	三嗪类	掺杂增加了表面积和生物炭上的—COOH和—PO₃基团的数量,从而促进吸附过程,来自玉米秸秆(CSWP)的掺杂生物炭,最大吸附量可达79.6 mg·g^-1	[21]
纳米石榴皮生物炭	毒死蜱	最大吸附量比石榴皮提高了25倍,10 min内吸附率约为90%	[41]
酸、碱、磁化改性700 ℃热解玉米秸秆生物炭	多菌灵	3种改性生物炭对多菌灵的吸附能力为磁化生物炭>酸化生物炭>碱化生物炭。磁化生物炭的最大吸附量达到108.1 mg·g^-1	[42]
黏土-白杨生物炭复合材料	草甘膦	复合材料比黏土和生物炭具有更好的吸附能力,吸附动力学符合准二级动力学模型,与 Langmuir模型拟合较好	[43]
载铁风车草生物炭	毒死蜱	铁浸渍的生物炭的表面比原始生物炭更复杂,更多孔,表现出比原始生物炭更高的吸附能力	[44]

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