Progress in photocatalytic degradation technology of pesticide and veterinary drug residues in water

doi:10.16178/j.issn.0528-9017.20250093

Abstract

Abstract:

The residues of pesticide and veterinary drugs in water will not only affect the growth of aquatic organisms, but also enter the human body through the food chain, endangering people's health. Among various degradation technologies, photocatalytic degradation technology has attracted wide attention because of its advantages of simple operation, low cost and no secondary pollution. According to the research progress of photocatalytic degradation technology in the degradation of pesticide and veterinary drug residues in water, this paper firstly introduced the principle of photocatalytic degradation technology and the properties and characteristics of main photocatalytic materials (such as metal oxides, metal sulfides, Bi-based photocatalyst and graphite-like phase g-C₃N₄, etc.), and expounded in detail the main modification methods of photocatalytic materials (including metal/nonmetal doping, defect engineering, photosensitization and heterojunction construction, etc.). The research progress of different photocatalytic materials in degrading residues of pesticide (such as organophosphorus, organochlorine, pyrethroids, etc.) and veterinary drugs (such as tetracycline and fluoroquinolones, etc.) in water was summarized.

Key words: photocatalysis, degradation technology, pesticide, veterinary drug, residues

CLC Number:

S481.1

ZHOU Yuteng, WANG Jiao, WU Nannan, LIU Zhenzhen, QI Peipei, GU Chengbo, WANG Xinquan. Progress in photocatalytic degradation technology of pesticide and veterinary drug residues in water[J]. Journal of Zhejiang Agricultural Sciences, 2025, 66(12): 3099-3108.

Figures/Tables 6

References 75

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农药	光催化剂	试验条件	降解率/%	参考文献
敌敌畏	Zn/TiO₂-OSP	催化剂2.0 g·L^-1,农药10.00 mg·L^-1,250 W紫外光240 min	100.0	[40]
敌敌畏	Co-MTiO₂	催化剂0.2 g·L^-1,农药20.00 mg·L^-1,pH值11,500 W紫外光180 min	97.0	[41]
辛硫磷	Zn/TiO₂-OSP	催化剂2.0 g·L^-1,农药10.00 mg·L^-1,250 W紫外光240 min	90.1	[40]
乙酰甲胺磷	Co-MTiO₂	催化剂0.2 g·L^-1,农药20.00 mg·L^-1,pH值11,500 W紫外光180 min	92.4	[41]
乙酰甲胺磷	Fe₃O₄@SiO₂@mTiO₂	催化剂0.1 g·L^-1,农药1.09×10^-4 mol·L^-1,100 W紫外光80 min	100.0	[42]
乐果	SnO₂-ZnO/煤矸石	催化剂1.0 g·L^-1,农药10.00 mg·L^-1,pH值为9,250 W紫外光180 min	100.0	[43]
马拉硫磷	SnO₂-ZnO/煤矸石	催化剂1.0 g·L^-1,农药10.00 mg·L^-1,pH值为9,250 W紫外光180 min	100.0	[43]
甲基对硫磷	Fe₃O₄@SiO₂@mTiO₂	催化剂0.1 g·L^-1,农药0.94×10^-4 mol·L^-1,100 W紫外光45 min	100.0	[42]
甲基嘧啶磷	Fe₃O₄@SiO₂@mTiO₂	催化剂0.1 g·L^-1,农药0.76×10^-4 mol·L^-1,100 W紫外光45 min	100.0	[42]

农药	光催化剂	试验条件	降解率/%	参考文献
敌敌畏	Zn/TiO₂-OSP	催化剂2.0 g·L^-1,农药10.00 mg·L^-1,250 W紫外光240 min	100.0	[40]
敌敌畏	Co-MTiO₂	催化剂0.2 g·L^-1,农药20.00 mg·L^-1,pH值11,500 W紫外光180 min	97.0	[41]
辛硫磷	Zn/TiO₂-OSP	催化剂2.0 g·L^-1,农药10.00 mg·L^-1,250 W紫外光240 min	90.1	[40]
乙酰甲胺磷	Co-MTiO₂	催化剂0.2 g·L^-1,农药20.00 mg·L^-1,pH值11,500 W紫外光180 min	92.4	[41]
乙酰甲胺磷	Fe₃O₄@SiO₂@mTiO₂	催化剂0.1 g·L^-1,农药1.09×10^-4 mol·L^-1,100 W紫外光80 min	100.0	[42]
乐果	SnO₂-ZnO/煤矸石	催化剂1.0 g·L^-1,农药10.00 mg·L^-1,pH值为9,250 W紫外光180 min	100.0	[43]
马拉硫磷	SnO₂-ZnO/煤矸石	催化剂1.0 g·L^-1,农药10.00 mg·L^-1,pH值为9,250 W紫外光180 min	100.0	[43]
甲基对硫磷	Fe₃O₄@SiO₂@mTiO₂	催化剂0.1 g·L^-1,农药0.94×10^-4 mol·L^-1,100 W紫外光45 min	100.0	[42]
甲基嘧啶磷	Fe₃O₄@SiO₂@mTiO₂	催化剂0.1 g·L^-1,农药0.76×10^-4 mol·L^-1,100 W紫外光45 min	100.0	[42]

农药	光催化剂	试验条件	降解率/%	参考文献
2,4-D	Fe-TiO₂	催化剂2.0 g·L^-1,农药10 mg·L^-1,pH值4.6,300 W模拟太阳光240 min	74.2	[44]
2,4-D	BiOI/BiOBr_0.9I_0.1	催化剂0.5 g·L^-1,农药10 mg·L^-1,可见光120 min	95.0	[45]
2,4-D	Ag/BiVO4	催化剂1.0 g·L^-1,农药20 mg·L^-1,可见光240 min	90.0	[38]
林丹	Ge-TiO₂	催化剂0.1 g·L^-1,农药2 mg·L^-1,pH值5.0,紫外光80 min	95.0	[46]

农药	光催化剂	试验条件	降解率/%	参考文献
2,4-D	Fe-TiO₂	催化剂2.0 g·L^-1,农药10 mg·L^-1,pH值4.6,300 W模拟太阳光240 min	74.2	[44]
2,4-D	BiOI/BiOBr_0.9I_0.1	催化剂0.5 g·L^-1,农药10 mg·L^-1,可见光120 min	95.0	[45]
2,4-D	Ag/BiVO4	催化剂1.0 g·L^-1,农药20 mg·L^-1,可见光240 min	90.0	[38]
林丹	Ge-TiO₂	催化剂0.1 g·L^-1,农药2 mg·L^-1,pH值5.0,紫外光80 min	95.0	[46]

农药	光催化剂	试验条件	降解率/%	参考文献
抗蚜威	Pt/AgInS₂	催化剂1.0 g·L^-1,农药10.0 mg·L^-1,pH值3.0,可见光24 h	98.00	[47]
呋喃丹	NaNbO₃-Au-Sn₃O₄	催化剂0.4 g·L^-1,农药0.1 mg·L^-1,太阳光120 min	73.00	[48]
功夫菊酯	nTiO₂	催化剂2.0 g·L^-1,农药10.0 mg·L^-1,500 W紫外光18 min	98.33	[49]
溴氰菊酯	nTiO₂	催化剂0.8 g·L^-1,农药10.0 mg·L^-1,500 W紫外光10 min	97.81	[49]
氟氯氰菊酯	C-Ce-TiO₂	催化剂1.3 g·L^-1,农药0.4 mg·L^-1,9 W日光灯30 min	92.00	[50]
阿特拉津	N/Fe-TiO₂	催化剂1.0 g·L^-1,农药10.0 mg·L^-1,pH值5.8,300 W太阳光360 min	90.30	[44]
吡虫啉	PANI/WO₃-CdS	催化剂30.0 g·L^-1,农药10.0 mg·L^-1,pH值3.0,可见光180 min	94.70	[51]