农业投入品中隐性成分筛查方法及应用

doi:10.16178/j.issn.0528-9017.20190642

浙江农业科学 ›› 2019, Vol. 60 ›› Issue (6): 974-981.DOI: 10.16178/j.issn.0528-9017.20190642

农业投入品中隐性成分筛查方法及应用

汪志威¹, 周思齐^1,2, 李非里², 吴声敢¹, 杨桂玲¹, 齐沛沛¹, 王祥云¹, 狄珊珊¹, 徐浩¹, 王新全^1,*

1.浙江省农业科学院农产品质量标准研究所农业农村部农药残留检测重点实验室浙江省农药残留检测与控制研究重点实验室,浙江杭州 310021;
2.浙江工业大学环境学院,浙江杭州 310021

收稿日期:2019-02-20 出版日期:2019-06-11
通讯作者: 王新全(1979—),男,黑龙江牡丹江人,研究员,博士,研究方向为农产品农药残留检测,E-mail:wangxinquan0@126.com。
作者简介:汪志威(1984—),男,浙江德清人,助理研究员,博士,研究方向为农药环境行为和残留分析,E-mail:wangzhiwei1106@126.com。
基金资助:
国家自然科学基金(21607133); 浙江省公益技术应用研究(LGN19B070001); 特色农产品全产业链安全风险管控(“一品一策”)重大专项(ZJNY2018001); 现代农业产业技术体系建设专项资金(CARS-29)

Received:2019-02-20 Online:2019-06-11

摘要/Abstract

摘要： 建立了农业投入品中农药隐性成分的筛查方法体系。基于气相色谱串联三重四级杆质谱(GC-MS/MS)和气相色谱串联三重四级杆质谱(LC-MS/MS)的多反应监测模式,建立215种农药目标物的多残留筛查方法,并辅以气相色谱-质谱全扫描模式的无目标筛查方法。方法优化了筛查农药的清单,包括已经或即将禁限用农药和农药隐性成分检出率较高的农药,并完善了以稀释为主的前处理方法。利用该方法对浙江多地生产基地和农资店抽检的农药制剂和肥料共90批次农业投入品进行隐性成分筛查,共筛查出20批次样品中含有未标注农药隐性成分,其中4批次样品判定为非故意添加,16批次样品确定为含有增强药效或增加功能的故意添加农药隐性成分。

关键词: 三重四级杆串联质谱, 农业投入品, 农药隐性成分, 筛查, 无目标筛查

中图分类号:

S132
O657.7

汪志威, 周思齐, 李非里, 吴声敢, 杨桂玲, 齐沛沛, 王祥云, 狄珊珊, 徐浩, 王新全. 农业投入品中隐性成分筛查方法及应用[J]. 浙江农业科学, 2019, 60(6): 974-981.

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农业投入品中隐性成分筛查方法及应用

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