浙江农业科学 ›› 2022, Vol. 63 ›› Issue (12): 2909-2913.DOI: 10.16178/j.issn.0528-9017.20213352
汪建妹1(
), 钱鸣蓉2, 杨桂玲1, 孙淑媛3,*()
收稿日期:2022-02-23
出版日期:2022-12-11
发布日期:2022-12-09
通讯作者:
孙淑媛
作者简介:孙淑媛,女,工程师,从事畜产品质量安全研究工作,E-mail:334553381@qq.com。基金资助:
Received:2022-02-23
Online:2022-12-11
Published:2022-12-09
摘要：
通过对槽料和湖羊组织样品中农药残留的分析,发现槽料中存在农药残留的污染,且含有中药渣的槽料中农药残留水平高于不含中药渣的槽料。对应的湖羊羊肉和羊肝中农药残留分析结果显示,在饲喂中药渣中的羊肉和羊肝中检测出部分农药,且氯氟氰菊酯和三唑酮在羊肝样品中存在超标现象。因此,针对中药渣育肥湖羊,需关注药渣中的农药对湖羊组织产品的安全影响。
中图分类号:
汪建妹, 钱鸣蓉, 杨桂玲, 孙淑媛. 槽料及湖羊肉肝中农药残留测定[J]. 浙江农业科学, 2022, 63(12): 2909-2913.
| 农药 | LOD/(mg·kg-1) | LOQ/(mg·kg-1) | 回收率/%(RSD/%) | |||
|---|---|---|---|---|---|---|
| 槽料 | 产品 | 槽料 | 产品 | 槽料 | 产品 | |
| 虫螨腈 | 0.1 | 0.01 | 0.3 | 0.03 | 73.5(4.3) | 70.5 (2.1) |
| 啶虫脒 | 0.1 | 0.05 | 0.3 | 0.15 | 85.1(3.2) | 80.4 (5.4) |
| 氯虫苯甲酰胺 | 0.1 | 0.01 | 0.3 | 0.03 | 84.7(2.1) | 82.0 (7.1) |
| 氟啶胺 | 0.1 | 0.05 | 0.3 | 0.15 | 78.5 (1.3) | 78.0 (5.4) |
| 多效唑 | 0.1 | 0.01 | 0.3 | 0.03 | 93.2(3.8) | 90.9 (6.2) |
| 二氯吡啶酸 | 0.1 | 0.08 | 0.3 | 0.24 | 72.3(2.1) | 77.1 (4.3) |
| 茚虫威 | 0.1 | 0.01 | 0.3 | 0.03 | 91.4(6.7) | 89.0 (2.3) |
| 联苯菊酯 | 0.1 | 0.05 | 0.3 | 0.15 | 81.7(3.9) | 82.6 (4.3) |
| 氯氟氰菊酯 | 0.1 | 0.05 | 0.3 | 0.15 | 85.7(5.9) | 88.2 (4.5) |
| 炔螨特 | 0.1 | 0.05 | 0.3 | 0.15 | 76.3(9.1) | 76.0 (6.3) |
| 三氯杀螨醇 | 0.1 | 0.05 | 0.3 | 0.15 | 81.6(2.7) | 88.9 (2.9) |
| 三唑磷 | 0.1 | 0.10 | 0.3 | 0.30 | 75.9(6.7) | 77.6 (4.9) |
| 三唑酮 | 0.1 | 0.10 | 0.3 | 0.30 | 82.5(4.3) | 86.3 (3.4) |
| 烯效唑 | 0.1 | 0.10 | 0.3 | 0.30 | 79.6(2.0) | 81.1 (4.5) |
| 溴氰菊酯 | 0.1 | 0.05 | 0.3 | 0.15 | 86.3(1.9) | 85.0 (7.1) |
| 多菌灵 | 0.1 | 0.01 | 0.3 | 0.03 | 87.5(6.1) | 84.2 (4.5) |
| 克百威 | 0.1 | 0.01 | 0.3 | 0.03 | 89.7(4.5) | 86.7 (5.1) |
| 螺螨酯 | 0.1 | 0.05 | 0.3 | 0.15 | 92.5(3.0) | 93.1 (2.3) |
| 氯菊酯 | 0.1 | 0.05 | 0.3 | 0.15 | 85.2(4.8) | 85.1 (5.1) |
| 水胺硫磷 | 0.1 | 0.07 | 0.3 | 0.21 | 83.7(10.5) | 83.1 (7.9) |
| 烯酰吗啉 | 0.1 | 0.01 | 0.3 | 0.03 | 93.2(0.5) | 90.0 (2.1) |
| 甲拌磷 | 0.1 | 0.05 | 0.3 | 0.15 | 73.4(5.6) | 74.3 (4.2) |
| 甲基立枯磷 | 0.1 | 0.05 | 0.3 | 0.15 | 79.8(4.2) | 76.7 (5.4) |
| 桔皮素 | 0.1 | 0.01 | 0.3 | 0.03 | 89.6(3.5) | 79.8 (6.5) |
| 己唑醇 | 0.1 | 0.05 | 0.3 | 0.15 | 75.8(7.4) | 79.9(5.6) |
| 2,4-二氯苯氧乙酸 | 0.1 | 0.05 | 0.3 | 0.15 | 71.8(5.6) | 70.5(9.5) |
| 烯酰吗啉 | 0.1 | 0.01 | 0.3 | 0.03 | 87.9(3.2) | 90.6(5.4) |
| 吡虫啉 | 0.1 | 0.05 | 0.3 | 0.15 | 84.3(5.3) | 86.7(5.4) |
| 哒螨灵 | 0.1 | 0.05 | 0.3 | 0.15 | 89.7(2.7) | 94.3(4.5) |
| 氯唑磷 | 0.1 | 0.05 | 0.3 | 0.15 | 71.4(7.3) | 77.4(6.0) |
表1 不同基质中30种农药的LOD、LOQ、回收率和RSD
| 农药 | LOD/(mg·kg-1) | LOQ/(mg·kg-1) | 回收率/%(RSD/%) | |||
|---|---|---|---|---|---|---|
| 槽料 | 产品 | 槽料 | 产品 | 槽料 | 产品 | |
| 虫螨腈 | 0.1 | 0.01 | 0.3 | 0.03 | 73.5(4.3) | 70.5 (2.1) |
| 啶虫脒 | 0.1 | 0.05 | 0.3 | 0.15 | 85.1(3.2) | 80.4 (5.4) |
| 氯虫苯甲酰胺 | 0.1 | 0.01 | 0.3 | 0.03 | 84.7(2.1) | 82.0 (7.1) |
| 氟啶胺 | 0.1 | 0.05 | 0.3 | 0.15 | 78.5 (1.3) | 78.0 (5.4) |
| 多效唑 | 0.1 | 0.01 | 0.3 | 0.03 | 93.2(3.8) | 90.9 (6.2) |
| 二氯吡啶酸 | 0.1 | 0.08 | 0.3 | 0.24 | 72.3(2.1) | 77.1 (4.3) |
| 茚虫威 | 0.1 | 0.01 | 0.3 | 0.03 | 91.4(6.7) | 89.0 (2.3) |
| 联苯菊酯 | 0.1 | 0.05 | 0.3 | 0.15 | 81.7(3.9) | 82.6 (4.3) |
| 氯氟氰菊酯 | 0.1 | 0.05 | 0.3 | 0.15 | 85.7(5.9) | 88.2 (4.5) |
| 炔螨特 | 0.1 | 0.05 | 0.3 | 0.15 | 76.3(9.1) | 76.0 (6.3) |
| 三氯杀螨醇 | 0.1 | 0.05 | 0.3 | 0.15 | 81.6(2.7) | 88.9 (2.9) |
| 三唑磷 | 0.1 | 0.10 | 0.3 | 0.30 | 75.9(6.7) | 77.6 (4.9) |
| 三唑酮 | 0.1 | 0.10 | 0.3 | 0.30 | 82.5(4.3) | 86.3 (3.4) |
| 烯效唑 | 0.1 | 0.10 | 0.3 | 0.30 | 79.6(2.0) | 81.1 (4.5) |
| 溴氰菊酯 | 0.1 | 0.05 | 0.3 | 0.15 | 86.3(1.9) | 85.0 (7.1) |
| 多菌灵 | 0.1 | 0.01 | 0.3 | 0.03 | 87.5(6.1) | 84.2 (4.5) |
| 克百威 | 0.1 | 0.01 | 0.3 | 0.03 | 89.7(4.5) | 86.7 (5.1) |
| 螺螨酯 | 0.1 | 0.05 | 0.3 | 0.15 | 92.5(3.0) | 93.1 (2.3) |
| 氯菊酯 | 0.1 | 0.05 | 0.3 | 0.15 | 85.2(4.8) | 85.1 (5.1) |
| 水胺硫磷 | 0.1 | 0.07 | 0.3 | 0.21 | 83.7(10.5) | 83.1 (7.9) |
| 烯酰吗啉 | 0.1 | 0.01 | 0.3 | 0.03 | 93.2(0.5) | 90.0 (2.1) |
| 甲拌磷 | 0.1 | 0.05 | 0.3 | 0.15 | 73.4(5.6) | 74.3 (4.2) |
| 甲基立枯磷 | 0.1 | 0.05 | 0.3 | 0.15 | 79.8(4.2) | 76.7 (5.4) |
| 桔皮素 | 0.1 | 0.01 | 0.3 | 0.03 | 89.6(3.5) | 79.8 (6.5) |
| 己唑醇 | 0.1 | 0.05 | 0.3 | 0.15 | 75.8(7.4) | 79.9(5.6) |
| 2,4-二氯苯氧乙酸 | 0.1 | 0.05 | 0.3 | 0.15 | 71.8(5.6) | 70.5(9.5) |
| 烯酰吗啉 | 0.1 | 0.01 | 0.3 | 0.03 | 87.9(3.2) | 90.6(5.4) |
| 吡虫啉 | 0.1 | 0.05 | 0.3 | 0.15 | 84.3(5.3) | 86.7(5.4) |
| 哒螨灵 | 0.1 | 0.05 | 0.3 | 0.15 | 89.7(2.7) | 94.3(4.5) |
| 氯唑磷 | 0.1 | 0.05 | 0.3 | 0.15 | 71.4(7.3) | 77.4(6.0) |
| 农药 | 不同样本中含量/(mg·kg-1) | |||||||||||||||||||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 001 | 002 | 003 | 004 | 005 | 006 | 007 | 008 | 009 | 010 | 011 | 012 | 013 | 014 | 015 | ||||||||||||||||
| 水胺硫磷 | 9.17 | 2.65 | ND | ND | 7.57 | 3.70 | ND | 6.94 | ND | ND | 2.12 | 3.63 | 3.93 | 2.77 | 2.09 | |||||||||||||||
| 烯酰吗啉 | 1.47 | 1.48 | ND | 1.47 | 1.48 | ND | ND | 1.48 | ND | ND | 1.46 | ND | ND | 1.47 | ND | |||||||||||||||
| 甲拌磷 | 4.28 | 6.34 | 16.2 | 18.9 | 5.16 | 5.91 | 16.2 | 6.00 | 16.5 | 5.51 | 7.23 | 4.25 | 7.27 | 6.47 | 6.81 | |||||||||||||||
| 吡虫啉 | ND | ND | 0.16 | ND | ND | ND | ND | ND | ND | ND | ND | 0.12 | ND | ND | ND | |||||||||||||||
| 唑螨酯 | 0.12 | 0.13 | ND | ND | 0.12 | ND | ND | ND | ND | ND | ND | 0.12 | ND | ND | ND | |||||||||||||||
| 甲基立枯磷 | ND | ND | 0.071 | ND | 0.07 | ND | ND | 0.07 | 0.02 | ND | ND | ND | ND | 0.004 | ND | |||||||||||||||
| 桔皮素 | 3.98 | 1.52 | ND | ND | 4.83 | 10.6 | ND | 6.74 | ND | 11.5 | 10.2 | 17.3 | 13.4 | 9.12 | 3.99 | |||||||||||||||
| 己唑醇 | ND | 1.06 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||||
| 2,4-二氯苯氧乙酸 | 0.27 | 0.31 | ND | ND | 0.29 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||||
| 哒螨灵 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | 0.04 | ND | ND | ND | |||||||||||||||
| 氯唑磷 | ND | ND | ND | ND | ND | ND | ND | 0.06 | ND | ND | ND | ND | ND | ND | ND | |||||||||||||||
| 虫螨腈 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||||
| 啶虫脒 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||||
| 氯虫苯甲酰胺 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||||
| 多效唑 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||||
| 氟啶胺 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||||
| 二氯吡啶酸 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||||
| 农药 | 016 | 017 | 018 | 019 | 020 | 021 | 022 | 023 | 024 | 025 | 026 | 027 | 028 | 029 | 030 | 031 | 032~043 | |||||||||||||
| 虫螨腈 | 7.26 | 13.6 | 15.6 | ND | 14.3 | ND | 19.9 | 4.70 | 19.8 | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||
| 啶虫脒 | 118 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||
| 氯虫苯甲酰胺 | 36.2 | 9.71 | 17.5 | 20.5 | 3.06 | 1.60 | ND | ND | 3.02 | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||
| 氟啶胺 | 16.7 | 28.6 | 17.6 | 1.64 | 2.81 | 25.0 | 12.8 | 1.53 | 3.79 | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||
| 多效唑 | 17.7 | ND | 21.1 | 17.5 | ND | 19.1 | 20.4 | ND | ND | ND | ND | ND | ND | ND | ND | 0.32 | ND | |||||||||||||
| 二氯吡啶酸 | 12.3 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||
| 茚虫威 | 4.10 | ND | 7.48 | ND | ND | ND | 16.1 | 1.43 | 20.5 | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||
| 联苯菊酯 | ND | 3.20 | ND | ND | 0.50 | ND | 0.45 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||
| 氯氟氰菊酯 | ND | ND | 0.33 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||
| 炔螨特 | 1.59 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||
| 三氯杀螨醇 | 13.6 | ND | 2.21 | ND | 1.97 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||
| 三唑磷 | ND | ND | ND | 0.12 | ND | ND | 0.12 | ND | 0.32 | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||
| 三唑酮 | ND | ND | ND | ND | 0.13 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||
| 烯效唑 | 1.57 | ND | 0.20 | ND | ND | ND | ND | 0.37 | ND | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||
| 溴氰菊酯 | ND | 0.12 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||
| 多菌灵 | ND | ND | ND | ND | ND | ND | 156 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||
| 克百威 | ND | ND | ND | ND | ND | 2.86 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||
| 氯菊酯 | ND | ND | ND | ND | ND | ND | 0.26 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||
| 水胺硫磷 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | 1.37 | ND | ND | ND | ND | ND | ND | |||||||||||||
| 唑螨酯 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | 3.34 | ND | ND | ND | ND | |||||||||||||
| 桔皮素 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | 0.54 | ND | ND | ND | ND | |||||||||||||
| 螺螨酯 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | 0.10 | ND | 0.11 | ND | ND | ND | |||||||||||||
表2 槽料中农残检出结果
| 农药 | 不同样本中含量/(mg·kg-1) | |||||||||||||||||||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 001 | 002 | 003 | 004 | 005 | 006 | 007 | 008 | 009 | 010 | 011 | 012 | 013 | 014 | 015 | ||||||||||||||||
| 水胺硫磷 | 9.17 | 2.65 | ND | ND | 7.57 | 3.70 | ND | 6.94 | ND | ND | 2.12 | 3.63 | 3.93 | 2.77 | 2.09 | |||||||||||||||
| 烯酰吗啉 | 1.47 | 1.48 | ND | 1.47 | 1.48 | ND | ND | 1.48 | ND | ND | 1.46 | ND | ND | 1.47 | ND | |||||||||||||||
| 甲拌磷 | 4.28 | 6.34 | 16.2 | 18.9 | 5.16 | 5.91 | 16.2 | 6.00 | 16.5 | 5.51 | 7.23 | 4.25 | 7.27 | 6.47 | 6.81 | |||||||||||||||
| 吡虫啉 | ND | ND | 0.16 | ND | ND | ND | ND | ND | ND | ND | ND | 0.12 | ND | ND | ND | |||||||||||||||
| 唑螨酯 | 0.12 | 0.13 | ND | ND | 0.12 | ND | ND | ND | ND | ND | ND | 0.12 | ND | ND | ND | |||||||||||||||
| 甲基立枯磷 | ND | ND | 0.071 | ND | 0.07 | ND | ND | 0.07 | 0.02 | ND | ND | ND | ND | 0.004 | ND | |||||||||||||||
| 桔皮素 | 3.98 | 1.52 | ND | ND | 4.83 | 10.6 | ND | 6.74 | ND | 11.5 | 10.2 | 17.3 | 13.4 | 9.12 | 3.99 | |||||||||||||||
| 己唑醇 | ND | 1.06 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||||
| 2,4-二氯苯氧乙酸 | 0.27 | 0.31 | ND | ND | 0.29 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||||
| 哒螨灵 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | 0.04 | ND | ND | ND | |||||||||||||||
| 氯唑磷 | ND | ND | ND | ND | ND | ND | ND | 0.06 | ND | ND | ND | ND | ND | ND | ND | |||||||||||||||
| 虫螨腈 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||||
| 啶虫脒 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||||
| 氯虫苯甲酰胺 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||||
| 多效唑 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||||
| 氟啶胺 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||||
| 二氯吡啶酸 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||||
| 农药 | 016 | 017 | 018 | 019 | 020 | 021 | 022 | 023 | 024 | 025 | 026 | 027 | 028 | 029 | 030 | 031 | 032~043 | |||||||||||||
| 虫螨腈 | 7.26 | 13.6 | 15.6 | ND | 14.3 | ND | 19.9 | 4.70 | 19.8 | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||
| 啶虫脒 | 118 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||
| 氯虫苯甲酰胺 | 36.2 | 9.71 | 17.5 | 20.5 | 3.06 | 1.60 | ND | ND | 3.02 | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||
| 氟啶胺 | 16.7 | 28.6 | 17.6 | 1.64 | 2.81 | 25.0 | 12.8 | 1.53 | 3.79 | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||
| 多效唑 | 17.7 | ND | 21.1 | 17.5 | ND | 19.1 | 20.4 | ND | ND | ND | ND | ND | ND | ND | ND | 0.32 | ND | |||||||||||||
| 二氯吡啶酸 | 12.3 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||
| 茚虫威 | 4.10 | ND | 7.48 | ND | ND | ND | 16.1 | 1.43 | 20.5 | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||
| 联苯菊酯 | ND | 3.20 | ND | ND | 0.50 | ND | 0.45 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||
| 氯氟氰菊酯 | ND | ND | 0.33 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||
| 炔螨特 | 1.59 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||
| 三氯杀螨醇 | 13.6 | ND | 2.21 | ND | 1.97 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||
| 三唑磷 | ND | ND | ND | 0.12 | ND | ND | 0.12 | ND | 0.32 | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||
| 三唑酮 | ND | ND | ND | ND | 0.13 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||
| 烯效唑 | 1.57 | ND | 0.20 | ND | ND | ND | ND | 0.37 | ND | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||
| 溴氰菊酯 | ND | 0.12 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||
| 多菌灵 | ND | ND | ND | ND | ND | ND | 156 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||
| 克百威 | ND | ND | ND | ND | ND | 2.86 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||
| 氯菊酯 | ND | ND | ND | ND | ND | ND | 0.26 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | |||||||||||||
| 水胺硫磷 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | 1.37 | ND | ND | ND | ND | ND | ND | |||||||||||||
| 唑螨酯 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | 3.34 | ND | ND | ND | ND | |||||||||||||
| 桔皮素 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | 0.54 | ND | ND | ND | ND | |||||||||||||
| 螺螨酯 | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | ND | 0.10 | ND | 0.11 | ND | ND | ND | |||||||||||||
图1 含中药渣槽料中农药检出率
图2 不含中药渣槽料中农药检出率
| 样品 编号 | 含量/(mg·kg-1) | |||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 多效唑 | 联苯菊酯 | 三唑酮 | 氯氟氰菊酯 | 样品编号 | 多效唑 | 联苯菊酯 | 三唑酮 | 氯氟氰菊酯 | ||||
| R-01 | ND | ND | ND | ND | G-01 | ND | ND | ND | ND | |||
| R-02 | ND | ND | ND | ND | G-02 | ND | ND | ND | ND | |||
| R-03 | ND | ND | ND | ND | G-03 | ND | ND | ND | ND | |||
| R-04 | ND | ND | ND | ND | G-04 | ND | ND | ND | ND | |||
| R-05 | ND | ND | ND | ND | G-05 | ND | ND | ND | ND | |||
| R-06 | ND | ND | ND | ND | G-06 | ND | ND | ND | ND | |||
| R-07 | ND | ND | ND | ND | G-07 | ND | 0.061 | ND | ND | |||
| R-08 | 0.032 | ND | ND | ND | G-08 | 0.095 | ND | 0.03 | ND | |||
| R-09 | ND | ND | ND | ND | G-09 | ND | ND | ND | 0.07 | |||
| R-10 | ND | ND | ND | ND | G-10 | ND | ND | ND | ND | |||
| R-11 | ND | ND | ND | ND | G-11 | ND | ND | ND | ND | |||
| 样品 编号 | 含量/(mg·kg-1) | |||||||||||
| 多效唑 | 联苯菊酯 | 三唑酮 | 氯氟氰菊酯 | 样品编号 | 多效唑 | 联苯菊酯 | 三唑酮 | 氯氟氰菊酯 | ||||
| R-12 | ND | ND | ND | ND | G-12 | ND | ND | 0.07 | ND | |||
| R-13 | ND | ND | ND | ND | G-13 | ND | ND | ND | ND | |||
| R-14 | 0.013 | ND | ND | ND | G-14 | ND | ND | ND | ND | |||
| R-15 | ND | ND | ND | ND | G-15 | ND | ND | ND | ND | |||
| R-16 | ND | ND | ND | ND | G-16 | ND | ND | ND | ND | |||
| R-17 | ND | ND | ND | ND | G-17 | ND | ND | ND | ND | |||
| R-18 | 0.074 | ND | ND | ND | G-18 | 0.112 | ND | ND | ND | |||
| R-19 | ND | ND | ND | ND | G-19 | ND | ND | ND | ND | |||
| R-20 | ND | ND | ND | ND | G-20 | ND | ND | ND | ND | |||
| R-21 | ND | ND | ND | ND | G-21 | ND | ND | ND | ND | |||
| R-22 | ND | ND | ND | ND | G-22 | ND | ND | ND | ND | |||
| R-23 | ND | ND | ND | ND | G-23 | ND | ND | ND | ND | |||
| R-24 | ND | ND | ND | ND | G-24 | ND | ND | ND | ND | |||
| R-25 | ND | ND | ND | ND | G-25 | ND | ND | ND | ND | |||
| R-26 | ND | ND | ND | ND | G-26 | ND | ND | ND | ND | |||
| R-27 | ND | ND | ND | ND | G-27 | ND | ND | ND | ND | |||
| R-28 | ND | ND | ND | ND | G-28 | ND | ND | ND | ND | |||
| R-29 | ND | ND | ND | ND | G-29 | ND | ND | ND | ND | |||
表3 羊组织样品中农残检出结果
| 样品 编号 | 含量/(mg·kg-1) | |||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 多效唑 | 联苯菊酯 | 三唑酮 | 氯氟氰菊酯 | 样品编号 | 多效唑 | 联苯菊酯 | 三唑酮 | 氯氟氰菊酯 | ||||
| R-01 | ND | ND | ND | ND | G-01 | ND | ND | ND | ND | |||
| R-02 | ND | ND | ND | ND | G-02 | ND | ND | ND | ND | |||
| R-03 | ND | ND | ND | ND | G-03 | ND | ND | ND | ND | |||
| R-04 | ND | ND | ND | ND | G-04 | ND | ND | ND | ND | |||
| R-05 | ND | ND | ND | ND | G-05 | ND | ND | ND | ND | |||
| R-06 | ND | ND | ND | ND | G-06 | ND | ND | ND | ND | |||
| R-07 | ND | ND | ND | ND | G-07 | ND | 0.061 | ND | ND | |||
| R-08 | 0.032 | ND | ND | ND | G-08 | 0.095 | ND | 0.03 | ND | |||
| R-09 | ND | ND | ND | ND | G-09 | ND | ND | ND | 0.07 | |||
| R-10 | ND | ND | ND | ND | G-10 | ND | ND | ND | ND | |||
| R-11 | ND | ND | ND | ND | G-11 | ND | ND | ND | ND | |||
| 样品 编号 | 含量/(mg·kg-1) | |||||||||||
| 多效唑 | 联苯菊酯 | 三唑酮 | 氯氟氰菊酯 | 样品编号 | 多效唑 | 联苯菊酯 | 三唑酮 | 氯氟氰菊酯 | ||||
| R-12 | ND | ND | ND | ND | G-12 | ND | ND | 0.07 | ND | |||
| R-13 | ND | ND | ND | ND | G-13 | ND | ND | ND | ND | |||
| R-14 | 0.013 | ND | ND | ND | G-14 | ND | ND | ND | ND | |||
| R-15 | ND | ND | ND | ND | G-15 | ND | ND | ND | ND | |||
| R-16 | ND | ND | ND | ND | G-16 | ND | ND | ND | ND | |||
| R-17 | ND | ND | ND | ND | G-17 | ND | ND | ND | ND | |||
| R-18 | 0.074 | ND | ND | ND | G-18 | 0.112 | ND | ND | ND | |||
| R-19 | ND | ND | ND | ND | G-19 | ND | ND | ND | ND | |||
| R-20 | ND | ND | ND | ND | G-20 | ND | ND | ND | ND | |||
| R-21 | ND | ND | ND | ND | G-21 | ND | ND | ND | ND | |||
| R-22 | ND | ND | ND | ND | G-22 | ND | ND | ND | ND | |||
| R-23 | ND | ND | ND | ND | G-23 | ND | ND | ND | ND | |||
| R-24 | ND | ND | ND | ND | G-24 | ND | ND | ND | ND | |||
| R-25 | ND | ND | ND | ND | G-25 | ND | ND | ND | ND | |||
| R-26 | ND | ND | ND | ND | G-26 | ND | ND | ND | ND | |||
| R-27 | ND | ND | ND | ND | G-27 | ND | ND | ND | ND | |||
| R-28 | ND | ND | ND | ND | G-28 | ND | ND | ND | ND | |||
| R-29 | ND | ND | ND | ND | G-29 | ND | ND | ND | ND | |||
| [1] | 马吉荣. 湖羊舍饲养殖技术[J]. 兽医导刊, 2021(17): 111-112. |
| [2] | 王景. 浅谈湖羊的饲养管理[J]. 畜禽业, 2021, 32(11): 41-42. |
| [3] | 孙新琪, 安芳, 鹿倩, 等. 我国中药材禁用农药残留现状、毒性及分析方法研究进展[J]. 中国中药杂志, 2022, 47(3): 611-627. |
| [4] | 李得运, 于志斌. 2017年中药材进出口贸易分析[J]. 中国现代中药, 2018, 20(3): 345-348, 354. |
| [5] | 顾炎, 薛健, 金红宇, 等. 金银花中有机磷类农药测定方法建立及残留状况调查[J]. 中国现代中药, 2016, 18(9): 1148-1152. |
| [6] | 李家春, 伍静玲, 秦建平, 等. 基于QuEChERS法-超高效液相色谱-串联质谱法的5种中药材中35种有机磷农药残留量的快速分析[J]. 药物分析杂志, 2016, 36(1): 122-128. |
| [7] | 何清彦, 皮胜玲, 谢嘉驰, 等. GC-ECD测定当归等10种药食两用中药材中有机氯残留量[J]. 中国当代医药, 2016, 23(10): 4-7, 12. |
| [8] | SOJINU O S, SONIBARE O O, EKUNDAYO O O, et al. Assessment of organochlorine pesticides residues in higher plants from oil exploration areas of Niger Delta, Nigeria[J]. Science of the Total Environment, 2012, 433: 169-177. |
| [9] | 余新威, 王婕妤, 方力. 浙江省沿海棒锥螺中有机氯农药的含量及分布现状[J]. 中国卫生检验杂志, 2013, 23(13): 2739-2741. |
| [10] | 李慧君, 张文生, 吴洁珊, 等. 中药材农药残留研究现状[J]. 中国中药杂志, 2019, 44(1): 48-52. |
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